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I would use DVD X Copy gold which costs about 100.00. It will ask you if it's a rented movie and you just click no. There is also the Nero Burning software that is just incredible. you can actually take clips from your computer and make a movie with scene selections and menus.
DB, It would be better if you simply asked for the general purpose of burning any DVD movie rather than asking about a potnetially rented movie for your example. I don't think that discussing blatantly/potentially illegal actions is a good thing for any forum.